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Description, History, Bonuses and Features To start with, Playamo is a world-renowned Playtech provider. It was launched in, and since then has kept its supremacy in the slots market.Heteroaromatic dibenzothiophene-based ligands for development of new molecular materials: optical, thermal, electronic, and biological properties.

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A series of heteroaromatic dibenzothiophene-based ligands have been synthesized and evaluated as precursors for the formation of π-π interactions between their core moieties and metal/semiconductor nanoparticles. A comparison has been made between the optical, electronic, thermal, and biological properties of the new ligands. The novel ligands were designed to incorporate a 4-hydroxy-3-methoxyphenyl moiety to enhance the interligand conjugation. A detailed study has been carried out on the effect of the electron-withdrawing group (EWG), geometry, and rigid/flexible scaffold on the electronic, optical, thermal, and biological properties. The synthesized ligands have been used as the building blocks for the synthesis of new complexes. The ligands as well as their complexes were characterized using NMR, IR, electronic absorption spectroscopy, elemental analysis, X-ray diffraction, thermal analysis, and electrochemical analysis. The ligands have been analyzed using density functional theory (DFT) to calculate and predict their structural, thermal and electronic properties. Furthermore, the optical characteristics of the ligands and their metal/semiconductor complexes have been evaluated using UV-vis absorption spectra, which is useful for a better understanding of the photophysical processes in the optical limit. The anion sensing properties of the new compounds were investigated using absorption spectra, fluorescence measurements, and time-dependent fluorescence spectroscopy using p-nitrophenyl chloride as the target molecule. The synthesized ligands have been used to synthesize new complexes as biocides and anticancer agents. It was found that the ligands have promising biological activities compared with the literature data. The ligands and their corresponding complexes showed excellent photostability. The study showed that the complexes displayed moderate toxicity, which was retained after two rounds of biocidal activity tests. Moreover, the complexes were found to be stable over a long period of time and showed no degradation under nonirradiated conditions.Strategies for depression in healthcare professionals: A narrative review.


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